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Classification of alcohols.
All alcohols, а principle, can be divided into two
broad categories i.е. aliphatic alcohols and
aromatic alcohols.
1. Aliphatic alcohols. Alcohols in which the
hydroxyl group is linked an aliphatic carbon chain
are called aliphatic alcohols.
For example,
Methyl alcohol Ethyl alcohol Isopropyl alcohol
Methanol Ethanol 2-Propanol
2. Aromatic alcohols. Alcohols in which the hydroxyl group is present in the side
chain of an aromatic hydrocarbon are called aromatic For example.
phenylmethanol 2-phenylethanol
(benzyl alcohol) (-phenylethyl alcohol)
Alcohols are further classified as monohydric, dihydric, trihydric and
роlyhydric according as their molecules contain one, two, three, or many
hydroxyl groups respectively. For ехаmрlе,
Ethyl alcohol 1,2-Ethanediol 1,2,3-propanetriol
(Monohydric) (Dihydric) (Trihydric)
2. Aromatic alcohols. Alcohols in which the hydroxyl group is present in the side
chain of an aromatic hydrocarbon are called aromatic For example.
phenylmethanol 2-phenylethanol
(benzyl alcohol) (-phenylethyl alcohol)
Alcohols are further classified as monohydric, dihydric, trihydric and
роlyhydric according as their molecules contain one, two, three, or many
hydroxyl groups respectively. For ехаmрlе,
Ethyl alcohol 1,2-Ethanediol 1,2,3-propanetriol
(Monohydric) (Dihydric) (Trihydric)
I. Тhe alkyl alcohol system. In this system of common
nomenclature, the name of an alcohol is derived by combining
the name of the alkyl group with the word alcohol. The names
are mitten as two words.
n-butyl alcohol isobutyl alcohol tret-butyl alcohol
II. In this common system, the position of an additional substituent is
indicated by use of the Greek alphabet rather than by
numbers.
-chloroethyl alcohol -bromobutyl alcohol
Any simple radical that has а common name may be used in the
alkyl alcohol system, with one important exception. The grouping
С6Н5 - has the special name phenyl, but the compound C6H5OH is
phenol, not phenyl alcohol.
phenol
Substituted phenols are named as derivatives of the parent compound phenol.
The reason for this difference is historical and arose from the fact that phenol
and its derivatives have many chemical properties that are very different from
those of alkyl alcohols. However, phenyl substituted alkyl alcohols are normal
alcohols and often have common names. Examples are:
phenylmethanol 2-phenylethanol
(benzyl alcohol) ( -phenylethyl alcohol
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